By Frank C. Hawthorne, Roberta Oberti, Giancarlo Della Ventura, Annibale Mottana
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Additional info for Amphiboles: Crystal Chemistry, Occurrence, and Health Issues (Reviews in Mineralogy and Geochemistry 67)
957(6) Å] and Hanisch (1966) showed by polarized infrared spectroscopy that the O-H bond is orthogonal to (100). 775 Å in tremolite, Hawthorne and Grundy 1976], although this situation may change for short-range arrangements in Al-bearing amphiboles. O(3) = F. Above, we note that there is a hydrogen bond to the O(7) anion. Where O(3) = F, this hydrogen bond is no longer present, and as a consequence, the valence-sum rule (Brown 1981, 2002; Hawthorne 1994, 2006) predicts that the T(1)-O(7) distance should be slightly shorter in luorotremolite than in tremolite.
Geol 17:687-690 McGuire AV, Dyar MD, Nielson JE (1991) Metasomatic oxidation of upper mantle peridotite. Contrib Mineral Petrol 107:252-264 Mogessie A, Purtscheller F, Tessadri R (1986) High alumina calcic amphiboles (alumino pargasite-magnesio sadanagaite) from metabasites and metacarbonates of Central Oetztal, Eastern Alps (Northern Tyrol, Austria). N Jahrb Mineral Abh 154:21-39 Moore PB (1969) Joesmithite: a novel amphibole crystal chemistry. Mineral Soc Am Spec Pap 2:111-115 Moore PB, Davis AM, Van Derveer DG, Sen Gupta PK (1993) Joesmithite, a plumbous amphibole revisited and comments on bond valences.
606 Å, Cameron and Gibbs 1973, Si = 8 apfu). T(1) T(1) M(3) c O(3) T(2) T(2) M(1) M(1) T(1) T(1) b (b) a c Figure 33. The O(3) site in the C2/m amphibole structure; the O(3) site is shown by a black circle; (a) projected onto (100); (b) projected onto (010) with perspective and with the T(2) sites omitted for clarity, the H atom is shown by a small circle, and the H…O(7) hydrogen bond is shown by a dashed line. [Used by permission of Schweizerbart’sche Verlagsbuchhandlung, from Della Ventura et al.